Research Progress in [1,2]-Phospha-Brook Rearrangement Reaction
نویسندگان
چکیده
منابع مشابه
A radical thia-Brook rearrangement.
Geminal mercapto trialkyl- and trialkoxy-silanes undergo an efficient radical chain rearrangement, whereby the silyl group migrates from carbon to sulfur; the starting materials are readily obtained by exploiting the peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkyl- or trialkoxy-vinylsilanes.
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ژورنال
عنوان ژورنال: Daxue Huaxue
سال: 2020
ISSN: 1000-8438
DOI: 10.3866/pku.dxhx202008082